RadTech UV/EB Technology Conference & Expo 2008
May 4-7, 2008
Lakeside Center at McCormick Place
Chicago, Illinois - United States of America



HIGH PERFORMANCE COATINGS


High performance UV-curable coatings for different metal substrates
Svetlana Alexandra Bratslavsky, DSM Desotech

Abstract: UV-curable coatings were obtained from different types of oligomers: urethane acrylates, epoxy acrylates and cationically cured epoxies. Coatings were evaluated over flat metal substrates and wire. Physical-mechanical properties of UV cured coatings, as well as their low and high temperature stability were investigated. Coatings having good adhesion to copper, stainless steel, aluminum, and zinc-galvanized steel are discussed. Adhesion dependence on time, curing conditions and the adhesion promoters employed is shown.

Highly abrasion resistant UV curable clearcoat for plastics
Shan Cheng, PPG Industries, Inc.
Abstract: UV curable clearcoat technologies with enhanced abrasion resistance for plastic substrates are of current market and technical interests for industrial and optical products, such as consumer electronics, appliances, and ophthalmic lenses. A highly abrasion resistant UV curable hybrid coating technology has been developed offering significantly performance improvement as compared to state of the art commercial organic system. Formulation techniques, coating performance and application will be addressed in this paper.

Multicomponent Thiol-Ene Systems for Tailored Polymer Properties
Neil Cramer, University of Colorado
Abstract: This work investigates both the polymer properties and polymerization kinetics of ternary thiol-ene-(meth)acrylate photopolymer systems as high performance polymer and composite materials. Ternary thiol-ene-(meth)acrylate systems proceed via a mixed mode step-chain growth radical polymerization mechanism that combines the advantages of both step-growth thiol-ene and chain growth (meth)acrylate systems. They exhibit rapid polymerization kinetics, low oxygen inhibition, and high functional group conversion. Additionally, the polymer mechanical properties are tailorable over a wide range of values.

Photocuring of New Advanced Barrier Coatings
Sergei Nazarenko or Charles E. Hoyle, Univesity of Southern Mississippi
Abstract: Barrier materials that either restrict or selectively enhance gas or ion flow are extensively used. Traditional perm-selective barrier polymers are formed from thermoplastics and co-extruded polymer laminates. We have characterized a new class of advanced barrier materials that are readily photocured. These photocured films were found to exhibit significantly enhanced diffusion properties compared to traditional coatings and threefore offer significant processing advantages for replacing traditional barrier materials for,food packaging, electronics and other applications.

Potential Biofilm Resistant Coatings
Rebecca A. Herrington, Abilene Christian University
Abstract: Several potential biofilm resistant acrylates were synthesized and formulated, at varying weight percents, into standard UV-curable coatings. The formulations (4 mils thick) were UV-cured onto stainless steel plates where each coating's resistance to biofilm formation, adhesion, hardness, chemical and impact resistance were tested. Photo-differential scanning calorimetry was used to determine the polymerization rate of the acrylates (identical concentrations as formulations) in 1,6-hexanediol diacrylate using a standard Type I or II photoinitiator.

 

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